Heating the acyl azide in dry toluene under reflux for 3 hours ... | Filo
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SOLVED:(a) Define acyl chlorides, or acid chlorides. (b) Write structural formulas for four acid chlorides, and give their IUPAC names.
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Assertion: Acylation of amines gives a monosubstituted product whereas alkylation of amines gives polysubstituted product. Reason: Acyl group sterically hinders the approach of further acyl groups. - Chemistry | Shaalaa.com
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The Curtius rearrangement enables the conversion of acyl azides into isocyanates via thermally induced rearrangement with loss of dinitrogen. Developed by Theodor Curtius in the late 19th century, the reaction proceeds through rearrangement of the acyl azide to the isocyanate, and the resulting isocyanate can be trapped by nucleophiles to afford amines, carbamates, or ureas. Learn. Review. Repeat.
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